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Common irritants which are important causes of occupational dermatitis (tailored from [36, sixty six, 188]) Water and its additives (Salts and oxides of calcium, magnesium, and iron) Skin cleansers Soaps, detergents, “waterless cleansers, ”and components (sand, silica) Industrial cleaning Detergents, floor-energetic agents, agents sulfonated oils, wetting agents, emulsifiers, enzymes Alkalis Soap, soda, ammonia, potassium and sodium hydroxides, cement, lime, sodium silicate, trisodium phosphate, and numerous amines Acids Severe irritancy (caustic): sulfuric, hydrochloric, nitric, chromic, and hydrofluoric acids Moderate irritancy: acetic, oxalic, and salicylic acids Oils Cutting oils with numerous additives (water, emulsifiers, antioxidants, anticorrosive agents, preserva- tives, dyes and perfumes) Lubricating and spindle oils Organic solvents White spirit, benzene, toluene, trichloroethylene, perchloroethylene, methylene chloride, chloro- benzene Methanol, ethanol, isopropanol, propylene glycol Ethyl acetate, acetone, methyl ethyl ketone, ethylene glycol monomethyl ether, nitroethane, turpen- tine, carbon disulfide Thinners (mixtures of alcohols, ketones, and toluene) Oxidizing brokers Hydrogen peroxide, benzoyl peroxide, cyclohexanone peroxide, sodium hypochlorite Reducing agents Phenols, hydrazines, aldehydes, thioglycolates Plants Citrus peel and juice, flower bulbs, garlic, onion, pineapple, pelargonium, iris, cucumbers, butter- cups, asparagus, mustard, barley, chicory, corn Various crops of the spurge family (Euphorbiaceae), Brassicaceae family (Cruciferae) and Ranun- culaceae household (for additional particulars see [sixty one]) Animal products Pancreatic enzymes, bodily secretions Miscellaneous irritants Alkyl tin compounds and penta-, tetra-, and trichlorophenols (wooden preservatives) Bromine (in gasoline, agricultural chemicals, paper business, flame retardant) Methylchloroisothiazolinone and methylisothiazolinone (irritant at excessive concentrations throughout production or misuse) Components of plastic processing (formaldehyde, phenol, cresol, styrene, di-isocyanates, acrylic monomers, diallyl phthalate, aliphatic and aromatic amines, epichlorohydrin) Metal polishes Fertilizers Propionic acid (preservative in animal feed) Rust-preventive products Paint removers (alkyl bromide) Acrolein, crotonaldehyde, ethylene oxide, mercuric salts, zinc chloride, chlorine 262 Peter J. 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